Orpiment: Benefits, Uses & Dosage

Sanskrit: हरिताल • Botanical: Arsenic trisulphide (As2S3)

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Ayurvedic Properties

Taste (Rasa)
Pungent (Katu), Bitter (Tikta)
Quality (Guna)
Light (Laghu), Unctuous (Snigdha)
Potency (Virya)
Hot (Ushna)
Post-digestive (Vipaka)
Pungent (Katu)
Key Constituents
As2S3 (Arsenic trisulphide)
Also Known As
English: Orpiment, Yellow Arsenic
Sanskrit: हरिताल, नटी, पिञ्जर, गौरिपाषाण, तालक
Hindi: हरताल

What is Orpiment?

Orpiment is not a herb at all, and that is the first thing you should know about it. It is a bright yellow mineral, arsenic trisulphide (As2S3), known in English as Orpiment or Yellow Arsenic and in Sanskrit as Haritala (Haritala), with the Hindi name Hartal.

Classical Ayurveda took it seriously as medicine and as a danger. The Sushruta Samhita names it as one of the two mineral poisons, and the Bhavaprakash Nighantu (Varga 7) insists that it must be carefully purified before any use. That purification step is called Shodhana (Shodhana), a set of classical processing methods meant to reduce a substance's harmful effects.

The Bhavaprakash Nighantu describes two types: a foliated, flaky form (Patra Haritala), considered superior, and a massive, lumpy form (Pindi Haritala). It was used for skin diseases, vitiligo and worm infestations, applied externally for hair removal, and included in mineral-based preparations known as Rasa formulations (Rasa Aushadhi).

This page explains what the classical texts say. It is not a guide to using orpiment yourself. Orpiment is never for self-use.

Benefits of Orpiment

The classical texts describe several uses for orpiment. Read them as history and as the work of trained practitioners using purified material, not as a list of things to try at home.

Skin Conditions and Vitiligo

The Bhavaprakash Nighantu classes orpiment as Kushthahara (Kushthahara), meaning it acts against skin disease. Its pungent and bitter tastes (Katu, Tikta) and hot potency (Ushna Virya) are the properties Ayurveda associates with this kind of strong, clearing action.

The Sharangadhara Samhita records an external paste for leucoderma (white patches on the skin):

Talaka (orpiment) one Shana measure, Vakuchi (Psoralea corylifolia/Bakuchi) four Shanas, ground with cow's urine as a powder paste, this destroys leucoderma.

Sharangadhara Samhita, Uttara Khanda, Chapter 11: Lepa Vidhi

Hair Removal

The same chapter of the Sharangadhara Samhita lists orpiment as a depilatory paste ingredient, combined with conch shell powder (Shankha Churna).

For hair removal (Kesha Nashaka): two parts of conch shell powder (Shankha Churna) and one part Haritala (orpiment, arsenic trisulphide).

Sharangadhara Samhita, Uttara Khanda, Chapter 11: Lepa Vidhi

Worms and Parasites

Orpiment is classed as Krimighna (Krimighna), an agent against worms, and the Bhavaprakash Nighantu names worm infestations among its uses. This is why it is connected with parasites and worms in classical thinking.

Hiccups and Breathing

In the Charaka Samhita chapter on hiccups and breathlessness (Chikitsa Sthana, Chapter 17), orpiment appears as one of several ingredients in a medicated ghee prepared in the classical way.

Oral Disease

The Charaka Samhita (Chikitsa Sthana, Chapter 26) describes a mixture of realgar, orpiment, rock salt, Daruharidra bark and other ingredients, mixed with honey and ghee, held in the mouth for oral disease.

Rejuvenation and Debility

The Bhavaprakash Nighantu also lists orpiment as Rasayana (Rasayana), a rejuvenative, and as Vishaghna (Vishaghna), an anti-poison. This is the basis for its classical link to weakness and debility. That role belongs only to purified orpiment inside practitioner-made Rasa formulations.

How to Use Orpiment

You should not use orpiment yourself in any form. Every classical use assumes the mineral has first been purified (Shodhana) and then prepared by a trained practitioner. Our sources give no dose for personal use, and none should be guessed.

FormDoseBest ForWhen to Take
Rasa formulations (purified, practitioner-made)As directed by a practitionerClassical internal usesOnly under supervision
Medicated ghee (Charaka Samhita, Chikitsa 17)As directed by a practitionerClassical hiccup and breathing formulaOnly under supervision
External paste (Lepa)As directed by a practitionerClassical skin and hair-removal usesOnly under supervision

Why there is no home version

The Bhavaprakash Nighantu says orpiment, like realgar (Manahshila), must be carefully purified before use. Raw orpiment is arsenic trisulphide, which the Sushruta Samhita lists among the mineral poisons.

If you are interested in a formulation that contains it, speak with a qualified Ayurvedic practitioner and a medical doctor before taking anything.

Safety & Side Effects

Orpiment is an arsenic compound. Unlike most substances on this site, it is not a gentle herb with a few exceptions. It is a recognised poison in the classical texts themselves.

The milky exudations of Kumudaghni, Snuhi and Jala-Kshiri are poisons and are known as the three Kshira-Vishas, Phenasma-bhasma (white arsenic) and Haritala (yellow orpiment) are the two mineral poisons.

Sushruta Samhita, Kalpa Sthana, Chapter 2: Sthavara-Visha-Vijnaniya

What this means for you

  • Never self-medicate. Do not buy, take or apply raw orpiment.
  • Purification is required. The Bhavaprakash Nighantu says it must be carefully purified (Shodhana) before any use, and that work belongs to a trained practitioner.
  • External use is not a safe shortcut. Classical skin and hair-removal pastes were still practitioner preparations.
  • Get medical care. If you think you or someone else has swallowed or been exposed to orpiment, contact emergency services or a poison control centre.

Our sources do not list specific drug interactions or overdose signs, so this page does not guess at them. Any product containing orpiment should only be used under the supervision of a qualified Ayurvedic practitioner working with a medical doctor.

Orpiment vs Other Herbs & Supplements

Orpiment is a mineral, so it does not compare neatly with herbs. The useful comparisons are with the substances the classical texts name alongside it.

ComparisonOrpimentAlternativeVerdict
Orpiment vs Realgar (Manahshila)Yellow arsenic mineral, often paired with realgar in classical formulasRealgar, another arsenic mineral that the Bhavaprakash Nighantu also says must be purifiedNeither is for self-use. Both belong only in practitioner-made preparations.
Orpiment vs White Arsenic (Phenasma-bhasma)One of the two mineral poisons named by SushrutaThe other mineral poison in the same verseBoth are classed as poisons in the Sushruta Samhita. Avoid both.
Orpiment vs Bakuchi (Vakuchi) for leucodermaMinor ingredient (one part) in the classical pasteThe larger ingredient (four parts) in the same Sharangadhara Samhita pasteDo not make this paste at home. Ask a practitioner about safe options for white patches.

Our sources give no modern comparative research, so these rows describe classical context only.

Orpiment for Specific Populations

Classical sources give no population-specific guidance for orpiment. Because it is an arsenic compound listed among the mineral poisons, the guidance below is simple and cautious.

Pregnancy and Nursing

Do not use orpiment in any form during pregnancy or while nursing. Our sources contain no guidance supporting any use in these situations.

Children

Do not give orpiment to children in any form. Keep any product that may contain it out of reach.

Elderly

Although orpiment is listed as a rejuvenative (Rasayana), that classical role applies only to purified material in practitioner-made formulations. Older adults should not take it on their own.

Athletes

Our sources give no classical guidance for athletes, and no reason to use orpiment for performance or recovery. For any of these groups, consult a qualified practitioner and a medical doctor.

Frequently Asked Questions

Is orpiment a herb?

No. Orpiment is a yellow mineral, arsenic trisulphide (As2S3), also called Yellow Arsenic. It is grouped with herbs on this site only because the classical drug lists, such as the Bhavaprakash Nighantu, include minerals alongside plants.

Is orpiment poisonous?

Yes. The Sushruta Samhita names Haritala (yellow orpiment) as one of the two mineral poisons. Classical use depended on careful purification and practitioner preparation.

What is Shodhana?

Shodhana (Shodhana) is the classical purification process applied to minerals and toxic substances before use. The Bhavaprakash Nighantu says orpiment must be carefully purified, which is why it is never something to prepare at home.

What is the difference between Patra and Pindi Haritala?

Patra Haritala is the foliated, flaky form and Pindi Haritala is the massive, lumpy form. The Bhavaprakash Nighantu considers the foliated type superior.

Was orpiment really used for hair removal?

Yes. The Sharangadhara Samhita lists depilatory pastes of orpiment with conch shell powder, one version also with Palasha alkali. Do not make these yourself, since they contain an arsenic compound.

How to Use Orpiment by Condition

Explore how Orpiment is used for specific health concerns — with dosage, preparation methods, and classical references for each.

▶ Classical Text References (4 sources)

References in Astanga Hridaya Sutrasthan

13 Putpaka Dravyas भूशय सहानूपमेदोम जवसा मषैः नेहनं पयसा प टैःजीवनीयै च क पयेत ् Snehana Putapaka is done by making use of fat, marrow, muscle fat and juice of meat of animals which live in burrows (Bhushaya), which bite (Prasaha) – cut their food, cow, horse, ass etc, and those which live in Marshy lands (Anupa), or with drugs of Jivaneeya gana- (chapter 15) macerated with milk- 14 म ृगप य ु मांसमु ताय ता सै धवैः ोतोजराश खफेन आलैलखानं म तक ु ि कतैः Lekhana Putapaka is by making use of M

— Astanga Hridaya Sutrasthan, Tarpana Putpaka Vidhi

To this is added one Kudava (192 g) of ash of limestone, shells of mother of pearls, Kshirapaka (Khatika or clay), spiral of conch shell – each made red hot over a pan, fine powder of excreta of cock, peacock, falcon, heron and pigeon, bile of quadrupeds and birds, Ala ( haritala-Orpiment), Manohva (Realgar) and salts, all these are ground into a paste and mixed with the boiling solution, stirring it all the while from all sides.

— Astanga Hridaya Sutrasthan, Kshar-AgniKarma Vidhi

Source: Astanga Hridaya Sutrasthan, Tarpana Putpaka Vidhi; Kshar-AgniKarma Vidhi

References in Charaka Samhita

), alai (Haratala- yellow orpiment), are each taken in one karsha (12 gm) quantity and ghee in one prastha quantity and ghee is prepared in classical way.

— Charaka Samhita, Chikitsa Sthana — Therapeutic Principles, Chapter 17: Hiccup and Dyspnea Treatment (Hikka Shvasa Chikitsa / हिक्काश्वासचिकित्सा)

[194-196] Pitaka of manahshila (realgar), yavakshara, haratala (orpiment), saindhava (rock-salt), daruharidra bark mixed alongwith honey and ghee-scum and is kept in the mouth for cure of oral disease.

— Charaka Samhita, Chikitsa Sthana — Therapeutic Principles, Chapter 26: Three Vital Organs Treatment (Trimarmiya Chikitsa / त्रिमर्मीयचिकित्सा)

Source: Charaka Samhita, Chikitsa Sthana — Therapeutic Principles, Chapter 17: Hiccup and Dyspnea Treatment (Hikka Shvasa Chikitsa / हिक्काश्वासचिकित्सा); Chikitsa Sthana — Therapeutic Principles, Chapter 26: Three Vital Organs Treatment (Trimarmiya Chikitsa / त्रिमर्मीयचिकित्सा)

References in Sharangadhara Samhita

For hair removal (Kesha Nashaka): two parts of conch shell powder (Shankha Churna) and one part Haritala (orpiment, arsenic trisulphide).

— Sharangadhara Samhita, Uttara Khanda, Chapter 11: Lepa Vidhi (Topical Paste Application)

Orpiment (Haritala) is a traditional depilatory agent used in many ancient cultures.

— Sharangadhara Samhita, Uttara Khanda, Chapter 11: Lepa Vidhi (Topical Paste Application)

Another (depilatory) paste: Talaka (orpiment) two Shanas, Shankha Churna (conch shell powder) six Shanas, and Palasha Kshara (alkali of Butea monosperma) two Shanas -- grind together.

— Sharangadhara Samhita, Uttara Khanda, Chapter 11: Lepa Vidhi (Topical Paste Application)

Palasha Kshara (alkali ash of Butea monosperma) provides a strong alkaline medium that enhances the hair-dissolving action of orpiment.

— Sharangadhara Samhita, Uttara Khanda, Chapter 11: Lepa Vidhi (Topical Paste Application)

Another paste: Talaka (orpiment) one Shana measure, Vakuchi (Psoralea corylifolia/Bakuchi) four Shanas, ground with cow's urine as a powder paste -- this destroys leucoderma.

— Sharangadhara Samhita, Uttara Khanda, Chapter 11: Lepa Vidhi (Topical Paste Application)

Source: Sharangadhara Samhita, Uttara Khanda, Chapter 11: Lepa Vidhi (Topical Paste Application)

References in Sushruta Samhita

Garlands of sesame and rice grains, orpiment (Haritala), and Manashila (realgar) (should also be used).

— Sushruta Samhita, Uttara Tantra, Chapter 30: Shakunipratishedha

Vacha (Acorus calamus), Vayahstha, Golomi, orpiment (Haritala), realgar (Manashila), Kushtha (Saussurea lappa), and Sarjarasa (sal resin) -- this group is prescribed for preparing the oil.

— Sushruta Samhita, Uttara Tantra, Chapter 32: Putanapratishedha

Sura (liquor), Sauviraka (a fermented drink), Kushtha, orpiment (Haritala), and realgar (Manashila) (should also be used).

— Sushruta Samhita, Uttara Tantra, Chapter 33: Andhaputanapratishedha

The milky exudations of Kumudaghni, Snuhi and Jala-Kshiri are poisons and are known as the three Kshira-Vishas, Phenasma-bhasma (white arsenic) and Haritala (yellow orpiment) are the two mineral poisons.

— Sushruta Samhita, Kalpa Sthana, Chapter 2: Sthavara-Visha-Vijnaniya

The milky exudations of Kumudaghni, Snuhi and Jala-Kshiri are poisons and are known as the three Kshira-Vishas, Phenasma-bhasma (white arsenic) and Haritala (yellow orpiment) are the two mineral poisons.

— Sushruta Samhita, Sthavara-Visha-Vijnaniya

Source: Sushruta Samhita, Uttara Tantra, Chapter 30: Shakunipratishedha; Uttara Tantra, Chapter 32: Putanapratishedha; Uttara Tantra, Chapter 33: Andhaputanapratishedha; Kalpa Sthana, Chapter 2: Sthavara-Visha-Vijnaniya; Sthavara-Visha-Vijnaniya

Medical Disclaimer: The information on this page is for educational purposes only and is not intended as medical advice. Ayurvedic treatments should be pursued under the guidance of a qualified practitioner (BAMS/MD Ayurveda). Always consult your healthcare provider before starting any new treatment. Content is sourced from classical Ayurvedic texts and may not reflect the latest medical research.